Evidence of magmatic CO2-rich fluids in peraluminous graphite-bearing leucogranites from Deep Freeze Range (northern Victoria Land,Antarctica)     

Maria Luce Frezzotti  Gianfranco Di Vincenzo  Claudio Ghezzo  Ernst A. J. Burke 《Contributions to Mineralogy and Petrology》1994,117(2):111-123

Fine-grained peraluminous synkinematic leuco-monzogranites (SKG), of Cambro-Ordovician age, occur as veins and sills (up to 20–30 m thick) in the Deep Freeze Range, within the medium to high-grade metamorphics of the Wilson Terrane. Secondary fibrolite + graphite intergrowths occur in feldspars and subordinately in quartz. Four main solid and fluid inclusion populations are observed: primary mixed CO₂+H₂O inclusions + Al₂SiO₅ ± brines in garnet (type 1); early CO₂-rich inclusions (± brines) in quartz (type 2); early CO₂+CH₄ (up to 4 mol%)±H₂O inclusions + graphite + fibrolite in quartz (type 3); late CH₄+CO₂+N₂ inclusions and H₂O inclusions in quartz (type 4). Densities of type 1 inclusions are consistent with the crystallization conditions of SKG (750°C and 3 kbar). The other types are post-magmatic: densities of type 2 and 3 inclusions suggest isobaric cooling at high temperature (700–550°C). Type 4 inclusions were trapped below 500°C. The SKG crystallized from a magma that was at some stage vapour-saturated; fluids were CO₂-rich, possibly with immiscible brines. CO₂-rich fluids (±brines) characterize the transition from magmatic to post-magmatic stages; progressive isobaric cooling (T<670°C) led to a continuous decrease off _{O 2} can entering in the graphite stability field; at the same time, the feldspars reacted with CO₂-rich fluids to give secondary fibrolite + graphite. Decrease ofT andf _{O 2} can explain the progressive variation in the fluid composition from CO₂-rich to CH₄ and water dominated in a closed system (in situ evolution). The presence of N₂ the late stages indicates interaction with external metamorphic fluids.Contribution within the network Hydrothermal/metamorphic water-rock interactions in crystalline rocks: a multidisciplinary approach on paleofluid analysis. CEC program: Human Capital and Mobility  相似文献   

Heavy metals in stream sediments from copper and gold mining areas in southern Brazil     

Maria Heloisa D. Pestana  Milton L.L. Formoso  Elba C. Teixeir 《Journal of Geochemical Exploration》1997,58(2-3)

  相似文献   

Regional Seas and Sustainable Development Results of an International Workshop     

Josep Maria Bayona  Joan Albaigés 《GeoJournal》1995,36(4):416-416

Reports

Regional Seas and Sustainable Development Results of an International Workshop  相似文献   

Far-infrared observations of main sequence stars surrounded by dust shells     

P. M. Harvey  B. Smith  J. Di Francesco 《Astrophysics and Space Science》1995,224(1-2):475-476

We present 50 and 100µm photometry and size information for several main sequence stars surrounded by dust shells. The observations from NASA's Kuiper Airborne Observatory include the Vega-like stars, Beta Pic, Fomalhaut, as well as four stars suggested by Walker and Wolstencroft to belong possibly to the same class. The results of our observations are best interpreted as upper limits to the far-infrared sizes of the dust clouds around all of the stars except Fomalhaut and Beta Pic. We have also fit simple, optically thin models to the Beta Pic data to explore the range of shell parameters consistent with our limits and with previous observations.  相似文献   

Observation of MKN 501 at gamma-ray energies     

L. Bassani  R. C. Butler  A. J. Dean  G. Di Cocco  A. Della Ventura  F. Perotti  G. Villa 《Astrophysics and Space Science》1982,82(2):311-316

During a balloon flight in September 1979 of the MISO low-energy -ray telescope, the BL Lac-object MkN 501 was studied in the hard X-ray range above 30 keV and in the low energy -ray range up to 19 MeV. No statistically significant X- and -ray fluxes were detected. The implications of the upper limits obtained are discussed in the light of the relativistic jet theories recently proposed.  相似文献   

The nature of η carinae     

Roberto Viotti  Giovanni Battista Baratta  Anna Rosa Marenzi  Marcello Ranieri 《Astrophysics and Space Science》1990,169(1-2):95-100

We give an overview of the Car phenomenon on the basis of ground and space observations. We discuss in particular the IRAS images. We conclude that Car, initially with a mass > 100M , is presently an intermediate-type hypergiant withL=5×10⁶ L , in a rapid evolutionary stage. This phase started with a large increase of mass loss in mid-1800 followed by dust condensation and a large visual fading, at constant bolometric luminosity.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.  相似文献   

On the connection among three classical mechanical problems via the hypercomplex KS-transformation     

Maria Dina Vivarelli 《Celestial Mechanics and Dynamical Astronomy》1990,50(2):109-124

  相似文献   

Search for nucleosynthetic and radiogenic tellurium isotope anomalies in carbonaceous chondrites     

Manuela A. Fehr  Mark Rehkämper  Alex N. Halliday  Maria Schönbächler  Bodo Hattendorf 《Geochimica et cosmochimica acta》2006,70(13):3436-3448

Tellurium isotope data acquired by multiple-collector inductively coupled plasma-mass spectrometry (MC-ICPMS) are presented for sequential acid leachates of the carbonaceous chondrites Orgueil, Murchison, and Allende. Tellurium isotopes are produced by a broad range of nucleosynthetic pathways and they are therefore of particular interest given the isotopic anomalies previously identified for other elements in these meteorites. In addition, the data provide new constraints on the initial solar system abundance of the r-process nuclide ¹²⁶Sn, which decays to ¹²⁶Te with a half-life of 234,500 years. The ¹²⁶Te/¹²⁸Te ratios of all leachates were found to be identical, within uncertainty, despite variations in ¹²⁴Sn/¹²⁸Te of between about 0.002 and 1.4. The data define a ¹²⁶Sn/¹²⁴Sn ratio of <7.7 × 10⁻⁵ at the time of last isotopic closure, consistent with the value of <18 × 10⁻⁵ previously reported for bulk carbonaceous chondrites. How close this is to the initial ¹²⁶Sn/¹²⁴Sn ratio of the solar system depends on when the investigated samples last experienced redistribution of Sn and Te. No clear evidence is found for nucleosynthetic anomalies in the abundances of p-, s-, and r-process nuclides. The largest effect detected in this study is a small excess of the r-process nuclide ¹³⁰Te in a nitric acid leachate of Murchison. This fraction displays an anomalous ε¹³⁰Te of +3.5 ± 2.5. Although barely resolvable given the analytical uncertainties, this is consistent with the presence of a small excess r-process component or an s-process deficit. The general absence of anomalies contrasts with previous results obtained for K, Cr, Zr, Mo, and Ba isotopes in similar leachates, which display nucleosynthetic anomalies of up to 3.8%. The reason for this discrepancy is unclear but it may reflect volatility and more efficient mixing of Te in the solar nebula.  相似文献   

Response to the comment by V. Neck on “Hydrolysis of neptunium(V) at variable temperatures (10-85 °C)”, Geochimica et Cosmochimica Acta 68, 4821-4830     

Linfeng Rao  Thandankorai G. Srinivasan  PierLuigi Zanonato  Plinio Di Bernardo 《Geochimica et cosmochimica acta》2006,70(17):4556-4562

  相似文献   

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry     

Elisa Lopez Capel  Jos Maria de la Rosa Arranz  Francisco J. Gonzlez-Vila  Jos Antonio Gonzlez-Perez  David A.C. Manning 《Organic Geochemistry》2006,37(12):1983

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.  相似文献